Sweeping molecules with light

Manipulating molecules with quantum light.

It was first realized by Purcell (1) that the spontaneous emission rate of a quantum system can be enhanced or suppressed by placing it in a resonant radiofrequency cavity. Spontaneous emission as it was first theoretically described by Einstein (2) is not a pure property of matter. It is described by matter coupled to quantized radiation field modes, which can be manipulated in an artificial s...

Probing weakly bound molecules with nonresonant light.

We show that weakly bound molecules can be probed by "shaking" in a pulsed nonresonant laser field. The field introduces a centrifugal term which expels the highest vibrational level from the potential that binds it. Our numerical simulations applied to the Rb(2) and KRb Feshbach molecules indicate that shaking by feasible laser pulses can be used to accurately recover the square of the vibrati...

Sweeping with Continuous Domains

The geost constraint has been proposed to model and solve discrete placement problems involving multi-dimensional boxes (packing in space and time). The filtering technique is based on a sweeping algorithm that requires the ability for each constraint to compute a forbidden box around a given fixed point and within a surrounding area. Several cases have been studied so far, including integer li...

Light gives molecules the chills.

Shaping interactions between polar molecules with far-off-resonant light

We show that dressing polar molecules with a far-off-resonant optical field leads to new types of intermolecular potentials, which undergo a crossover from the inverse-power to oscillating behavior depending on the intermolecular distance, and whose parameters can be tuned by varying the laser intensity and wavelength. We present analytic expressions for the potential energy surfaces, thereby p...